(2,2′-Bipyridine-κ2N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ3O1,N,O2]copper(II)
نویسندگان
چکیده
منابع مشابه
(μ-Oxalato-κ4 O 1,O 2:O 1′,O 2′)bis[bis(2,2′-bipyridine-κ2 N,N′)cobalt(II)] μ6-oxido-dodeca-μ2-oxido-hexaoxido-hexatungstate(VI)
The asymmetric unit of the title compound, [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)][W(6)O(19)], consists of one half of the complex [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)](2+) cation and one half of the Lindqvist-type [W(6)O(19)](2-) isopolyanion. Both constituents are completed by crystallographic inversion symmetry. In the dimeric cation, the Co(II) atom is surrounded in a distorted octa-hedral coordi...
متن کامل(2,2′-Bipyridine-κ2 N,N′)[N-(2-oxido-1-naphthylidene)threoninato-κ3 O 1,N,O 2]copper(II)
In the title complex, [Cu(C(15)H(13)NO(4))(C(10)H(8)N(2))], the Schiff base ligand is derived from the condensation of 2-hydr-oxy-1-naphthaldehyde and l-threonine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 2,2'-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of int...
متن کامل4,4′-Bipyridine–2-methoxybenzoic acid (1/2)
The asymmetric unit of the title compound, C(10)H(8)N(2)·2C(8)H(8)O(3), contains two 2-meth-oxy-benzoic acid mol-ecules and one 4,4'-bipyridine mol-ecule. The 4,4'-bipyridine mol-ecule is disordered over two positions in a 1:1 ratio. In the crystal, the 2-meth-oxy-benzoic acid and 4,4'-bipyridine mol-ecules are connected by inter-molecular O-H⋯N hydrogen bonds. The dihedral angle between the ca...
متن کاملTris(2,2′-bipyridine)cobalt(II) μ6-oxido-dodeca-μ2-oxido-hexaoxidohexamolydate(VI)
In the title compound, [Co(C(10)H(8)N(2))(3)][Mo(6)O(19)], the Co(2+) cation is surrounded in a distorted octa-hedral coordination by six N atoms from three 2,2'-bipyridine ligands. The distribution of Mo-O bond lengths in the Lindqvist isopolyanion is consistent with other structures containing the same unit. In the crystal, the cations and anions are linked by C-H⋯O inter-actions.
متن کامل2-Aminoterephthalic acid–4,4′-bipyridine (1/1)
The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(7)NO(4), contains two half-mol-ecules, which constitute a 1:1 co-crystal. The 2-amino-terephthalic acid mol-ecule is situated on an inversion center being disordered between two orientations in a 1:1 ratio. In the 4,4'-bipyridine mol-ecule, which is situated on a twofold rotational axis, the two pyridine rings form a dihedral angle ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808012191